Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 9, Pages 4096-4099Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja300453u
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Funding
- NSFC [20872157, 21172236]
- CAS
- 973 Program [2010CB833200, 2011CB710800]
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A kinetic resolution of a-allenic alcohols is realized through chiral silver phosphate-catalyzed cycloisomerization with high stereoselectivity (selectivity factor up to 189) and tolerance of a variety of functional groups. A mechanistic model is proposed to interpret the origin of the high stereoselectivity and broad substrate scope.
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