Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 16, Pages 6900-6903Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja211141p
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Funding
- National Science Foundation [DMR-1104650]
- NIH [T32 GM008365]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1104650] Funding Source: National Science Foundation
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Nano- and micrometer-scale crystals of a self-assembled hexamer have been synthesized via sonochemistry. The application of ultrasonic irradiation afforded hollow rhombic-dodecahedral crystals of the C-methylcalix[4]resorcinarene hexamer. The formation of the hollow crystals is attributed to a reversed crystal growth mechanism heretofore described only in the synthesis of inorganic-based materials.
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