Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 20, Pages 8314-8317Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja300655f
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- FWO (Belgium)
- Belgian Prodex Office
- Flemish Government (Methusalem)
- Dutch National Science Foundation (NWO-CW-VENI)
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The metal organic framework NH2-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.
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