Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 6, Pages 1734-1737Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1109826
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Funding
- German Research Foundation (DFG) on Metal-Organic Frameworks [SPP 1362]
- Research Department Interfacial Systems Chemistry (IFSC) of the Ruhr University
- Alexander von Humboldt Foundation
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Layer-selective installation of functional groups at SURMOFs (surface-attached metal organic framework multilayers) is reported. Multilayers of [Cu(ndc)-(dabco)(0.5)] grown in [001] orientation on pyridine-terminated organic self-assembled monolayers on Au substrates were functionalized with amino groups by step-by-step liquid-phase epitaxy. The method allows the growth of samples exhibiting one monolayer of functional groups at the external thin-film surface. In situ quartz crystal microbalance monitoring confirmed the presence of amino groups by turning the multilayer film from a non-reactive to a reactive material for covalent binding of fluoresceinisothiocyanate, and fluorescence microscopy displays the expected luminous property.
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