4.8 Article

Light-Harvesting Metal-Organic Frameworks (MOFs): Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 40, Pages 15858-15861

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja206029a

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Funding

  1. U.S. DOE's Office of Science [DE-FG-87ER13808]
  2. AFOSR [FA-9550-07-1-0534]

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A pillared-paddlewheel type metal-organic framework material featuring bodipy- and porphyrin-based struts, and capable of harvesting light across the entire visible spectrum, has been synthesized. Efficient-essentially quantitative-strut-to-strut energy transfer (antenna behavior) was observed for the well-organized donor-acceptor assembly consituting the ordered MOF structure.

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