Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 20, Pages 7652-7655Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja202563w
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Funding
- Scripps Research Institute
- Korean Government [NRF-2009-352-C00077]
- Agency for Science, Technology and Research (A*STAR) Singapore
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C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with benzoyl peroxide in a one-pot procedure that proceeds via the in situ generation of the appropriate O-benzoyl hydroxylamines. This catalytic reaction provides a new disconnection for the convergent synthesis of tertiary and secondary arylalkyl amines starting from benzoic acids.
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