Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 10, Pages 3249-3251Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja109794p
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [20108010]
- NRF/MEST through CRI
- NRF/MEST through GRL [2010-00353]
- NRF/MEST through WCU [R31-2008-000-10010-0]
- Grants-in-Aid for Scientific Research [20108001, 20108010] Funding Source: KAKEN
- National Research Foundation of Korea [2010-00353, R31-2011-000-10010-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The photocatalytic formation of a non-heme oxoiron (IV) complex, [(N4Py)Fe(IV)(O)](2+) [N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine], efficiently proceeds via electron transfer from the excited state of a ruthenium complex, [Ru(II)(bpy)(3)](2+)* (bpy = 2,2'-bipyridine) to [Co(III)(NH(3))(5)Cl](2+) and stepwise electron-transfer oxidation of [(N4Py)Fe(II)](2+) with 2 equiv of [Ru(III)(bpy)(3)](3+) and H(2)O as an oxygen source. The oxoiron(IV) complex was independently generated by both chemical oxidation of [(N4Py)Fe(II)](2+) with [Ru(III)(bpy)(3)](3+) and electrochemical oxidation of [(N4Py)Fe(II)](2+).
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