Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 20, Pages 7668-7671Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja201425e
Keywords
-
Categories
Funding
- National Basic Research Program of China [2009CB825300]
- CAS
- Croucher Foundation
Ask authors/readers for more resources
DFT calculations suggest that the unexpected meta product in the copper-catalyzed arylation of anilide is formed via a Heck-like four-membered-ring transition state involving a Cu(III)-Ph species. A competitive electrophilic substitution mechanism delivers the ortho product when a methoxy group is present at the meta position of pivanilide. A series of experiments including kinetic studies support the involvement of a Cu(I) catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available