4.8 Article

Tuning the Relative Concentration Ratio of Bulk Defects to Surface Defects in TiO2 Nanocrystals Leads to High Photocatalytic Efficiency

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 41, Pages 16414-16417

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja207826q

Keywords

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Funding

  1. National Basic Research Program of China [2009CB939704]
  2. Ministry of Education of China [309021]
  3. Innovative Research Team Project of Hubei Province [2010CDA070]
  4. National Natural Science Foundation [51032005]

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TiO2 nanocrystals with tunable bulk/surface defects were synthesized and characterized with TEM, XRD, BET, positron annihilation, and photocurrent measurements. The effect of defects on photocatalytic activity was studied. It was found for the first time that decreasing the relative concentration ratio of bulk defects to surface defects in TiO2 nanocrystals could significantly improve the separation efficiency of photogenerated electrons and holes, thus significantly enhancing the photocatalytic efficiency.

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