Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 34, Pages 13252-13255Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204820d
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Funding
- Northwestern Institute for Catalysis in Energy Processes (U.S. Department of Energy) [DE-FG02-03ER15457]
- Northwestern NSEC
- DTRA [HDTRA1-09-01-0007]
- AFOSR [FA-9550-07-1-0534]
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A series of metallosalen-based metal organic frameworks (MOFs) have been prepared by the post-synthesis modification of (MnSO)-S-III-MOF, a Mn3+(salen)-based MOF. Treatment of (MnSO)-S-III-MOF with H2O2 effects the removal of the Mn3+ ions from the salen struts, which can then be remetalated with a variety of metal precursors to form iso-structural MSO-MOF materials. The presence of the new metallosalen struts in MSO-MOF was fully confirmed by ICP-OES, MALDI-TOF MS, PXRD, and TGA. Furthermore, the remetalated (MnSO)-S-II-MOF material displays similar catalytic activity and porosity to the parent MOF.
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