Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 38, Pages 14944-14947Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja206837j
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Funding
- 973 Program [2010CB833201, 2009CB940904]
- National Science and Technology Major Project [2009ZX10004-016]
- NSFC [21172009, 20832003, 20902007, 91013004]
- Shenzhen Basic Research Program [JC200903160352A, JC201005260097A, CXB201005260053A]
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Development of a gold-catalyzed tandem reaction of 1,7-diynes with both internal and external nucleophiles was realized, which constructed five chemical bonds, two rings, and two stereogenic centers in a single step. Based on the novel cascade transformation, we achieved a unified strategy toward the stereoselective total syntheses of C-15 oxygenated drimane-type sesquiterpenoids and their analogues, which provided the natural products kuehneromycin A, antrocin, anhydromarasmone, and marasmene as a proof-of-concept study.
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