Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 5, Pages 1266-1269Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1097995
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Funding
- EPSRC [EP/F008384/1]
- EPSRC [EP/F008384/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F008384/1] Funding Source: researchfish
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Crystalline microporous cobalt and nickel bisphosphonates with a hexagonal array of one-dimensional channels 1.8 nm in diameter have been prepared hydrothermally and provide the first example of the use of isoreticular chemistry in the synthesis of phosphonate metal-organic frameworks. The materials contain both physisorbed and coordinating water molecules in the as-prepared form, but these can be removed to give permanent extra-large microporosity, with pore volumes of up to 0.68 cm(3) g(-1), coordinatively unsaturated sites, with concentrations up to 4.25 mmol g(-1).
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