Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 1, Pages 115-118Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2095975
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- MEXT, Japan
- Grants-in-Aid for Scientific Research [22245016, 23685021] Funding Source: KAKEN
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The reaction of aryl cyanides with diboron in the presence of a rhodium/Xantphos catalyst and DABCO affords arylboronic esters via carbon-cyano bond cleavage. This unprecedented mode of reactivity for a borylrhodium species allows the regioselective introduction of a boryl group in a late stage of synthesis.
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