Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 1, Pages 30-31Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja109671f
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Funding
- EPSRC
- DSTL
- EPSRC [EP/D076552/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/D076552/1] Funding Source: researchfish
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We have synthesized a fused tetraanthracenylporphyrin by oxidation of a meso-anthracenyl nickel(11) porphyrin with FeCl3. This compound exhibits an intense red-shifted absorption spectrum (lambda(max) = 1417 nm; epsilon = 1.2 x 10(5) M-1 cm(-1)) and a small electrochemical HOMO-LUMO gap (0.61 eV). The crystal structure shows that it forms pi-stacked dimers with a short Ni center dot center dot center dot Ni distance (3.32 angstrom).
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