Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 42, Pages 16806-16808Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2079064
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Funding
- KAKENHI, Japan Society for the Promotion of Science
- JSPS
- Grants-in-Aid for Scientific Research [23750146, 11J09475] Funding Source: KAKEN
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In the pore of a porous coordination network, Diels-Alder reactants, a diene and a dienophile, are recognized by donor-acceptor and multiple H-bond interactions, respectively, and fixed at ideal positions for the reaction. Heating the crystals promoted the Diels-Alder reactions with enhanced reactivity and controlled regioselectivity as clearly monitored by in situ X-ray crystallography.
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