4.8 Article

Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 31, Pages 11952-11955

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja205046h

Keywords

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Funding

  1. MICINN [CTQ2010-16088/BQU, CSD2006-0003]
  2. FPI
  3. AGAUR [2009 SGR 47]
  4. ICIQ Foundation

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Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.

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