Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 28, Pages 10756-10759Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204226n
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Funding
- National Science Foundation of China [20832002, 21072223]
- Fundamental Research Funds for the Central Universities
- Renmin University of China [10XNL017]
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A three-component reaction of alkenes, aldehydes, and hydroperoxides catalyzed by FeCl2 to beta-peroxy ketones has been achieved. This three-component reaction can be also applied to the synthesis of a-carbonyl epoxides, through either a stepwise base-induced epoxidation of the separated beta-peroxy ketone products or a one-pot process by simply adding base to the reaction mixture after the completion of the three-component reaction.
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