Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 45, Pages 18003-18005Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja207851s
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Funding
- JSPS
- Ministry of Education, Culture, Sports, Science and Technology of Japan [22000006, 21659024, 21750135]
- Inoue Foundation for Science
- Research Foundation for Pharmaceutical Sciences
- Konica Minolta Science and Technology Foundation
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [22590258, 22000006, 23659089, 21659024, 10J10626, 21750135, 23790316] Funding Source: KAKEN
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Hydrogen sulfide (H2S) has recently been identified as a biological response modifier. Here, we report the design and synthesis of a novel fluorescence probe for H2S, HSip-1, utilizing azamacrocyclic copper(II) ion complex chemistry to control the fluorescence. HSip-1 showed high selectivity and high sensitivity for H2S, and its potential for biological applications was confirmed by employing it for fluorescence imaging of H2S in live cells.
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