Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 4, Pages 748-751Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja110042b
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Funding
- Major State Basic Research Development Programs [2011CB808704, 2007CB936302]
- NSFC [20771058, 20931004]
- Science Foundation of Innovative Research Team of NSFC [20721002]
- Natural Science Foundation of Jiangsu Province in China [BK2009228]
- Ministry of Education of China [200802840011]
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An rht-type metal organic framework (MOF) prepared from M-2(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C-3-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO2 uptake, an enhanced heat of adsorption, and higher selectivity toward CO2/N-2 in comparison with what was previously observed for an analogous MOF with alkyne groups.
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