Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 11, Pages 3816-3819Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja200329p
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Funding
- NSFC [21025101, 20871006, 20821091]
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Monodisperse single-crystalline sub-10 nm Pt-Pd nanotetrahedrons (NTs) and nanocubes (NCs) were synthesized with high shape selectivity via one-pot hydrothermal routes with small ions as efficient facet-selective agents. These alloy nanocrystals showed facet-dependent enhanced electrocatalytic activity and durability for methanol electrooxidations with commercial Pt/C catalyst as a reference. The (100)-facet-enclosed Pt-Pd NCs demonstrated a higher activity, whereas the (111)-facet-enclosed Pt-Pd NTs exhibited a better durability.
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