Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 51, Pages 20680-20683Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja208555h
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- Ministry of Education, Singapore [ARC25/08]
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We report the use of a simple complex assembled from Ni(II) salt and 2-mecaptoethanol in one step in water as the efficient catalyst in a molecular hydrogen system which can be sensitized by a low-cost xanthene dye, Erythrosin B. An excellent quantum efficiency of 24.5% is attained at 460 nm. This simple system is expected to contribute toward the development of economical and environmentally benign solar hydrogen production systems.
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