Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 11, Pages 3828-3831Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja200368y
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- Caltech
- BP
- NSF GRFP
- NSF CRIF:MU [CHE-063-9094]
- NIH [RR027690]
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Nickel hydrides supported by a terphenyl diphosphine were synthesized and found to undergo nickel-to-arene H-transfers. Some of the resulting complexes also undergo the reverse (C-to-Ni) H-migration, indicating the potential for storing H-equivalents in this type of pincer ligand. NMR spectroscopy, single crystal X-ray diffraction, and isotopic labeling studies investigating the mechanism of these processes are discussed.
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