Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 10, Pages 3222-3225Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107645c
Keywords
-
Categories
Funding
- U.S. Army Research Laboratory
- U.S. Army Research Office [W911NF-07-1-0409]
- ACS Division of Organic Chemistry Schering-Plough Fellowship
Ask authors/readers for more resources
Tension along a polymer chain traps neighboring s-trans/s-trans-1,3-diradicals from the mechanically induced ring opening of gem-difluorocyclopropanes (gDFCs). The diradicals correspond to the transition states of the force-free thermal isomerization reactions of gDFCs, and the tension trapping allows a new disproportionation reaction between two simultaneously trapped diradicals to take place.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
