Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 28, Pages 10700-10703Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja202316m
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Funding
- National Science Foundation [CHE-0848248, CHE-0645381]
- Alexander von Humboldt Stiftung
- CONACYT
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848248] Funding Source: National Science Foundation
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The transient titanium alkylidyne, (PNP)Ti (CBu)-Bu-t (PNP = N[2-(PPr2)-Pr-i-4-methylphenyl](2)(-)), activates a C-H bond of ethane at room temperature, and a beta-hydrogen of the resulting ethyl ligand is subsequently transferred to the adjacent alkylidene ligand to form an ethylene adduct of titanium. Treatment of the ethylene complex with two-electron oxidants such as organic azides results in extrusion of ethene concomitant with formation of a mononuclear titanium imido complex.
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