Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 34, Pages 13308-13310Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204861a
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Funding
- NSF [CHE-0952753]
- Massachusetts Life Science Center
- NIH-NIGMS [GM088237]
- Merck
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0952753] Funding Source: National Science Foundation
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A silver-mediated cross-coupling of trifluoromethoxide with aryl stannanes and arylboronic acids to give aryl trifluoromethyl ethers is reported. This is the first report of a transition-metal-mediated C-aryl-OCF3 bond formation.
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