Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 48, Pages 19354-19357Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja209373k
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Funding
- National Nature Science Foundation of China [20972095, 21172143]
- Science and Technology Commission of Shanghai Municipality [10dz1910105]
- Nippon Chemical Industrial Co., Ltd.
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Hydrogen-bond-activated C-N bond cleavage of allylic amines was realized in Pd-catalyzed allylic alkylation to form the C-C bond product. The method could be expanded to a series of allylic amines and carbonyl compounds with excellent results. It provides a new and convenient access to C-C bond formation based on Pd-catalyzed allylic alkylation of allylic amines by using only inexpensive alcohol solvents.
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