Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 5, Pages 1162-1164Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107849y
Keywords
-
Categories
Funding
- ACS PRF [49817-ND1]
- NIH [GM095666, RR08389-01]
- Sloan Foundation
- Beckman Foundation
- Research Corporation
- NSF [CHE-9208463, CHE-9629688]
Ask authors/readers for more resources
We report a new method for the formal [3+2] reaction of aryl cyclopropyl ketones with olefins to generate highly substituted cyclopentane ring systems. The key initiation step in this process is the one-electron reduction of the ketone to the corresponding radical anion, which is accomplished using a photocatalytic system comprising Ru(bpy)(3)(2+), La(OTf)(3), and TMEDA.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available