Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 45, Pages 18058-18061Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja207638h
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Funding
- National Science Foundation [CHE-0718030, CHE-1055505]
- Cornell University
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1055505] Funding Source: National Science Foundation
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Typical C-C bond-forming processes feature oxidative addition, insertion, and reductive elimination reactions. An alternative strategy toward C-C bond formation involves the generation of transient radicals that can couple at or around one or more metal centers. Generation of transient azaallyl ligands that reductively couple at CH positions possessing radical character is described. Two C-C bonds form, and the redox non-innocence of the resulting pyridine-imines may be critical to formation of a third C-C bond via dinuclear di-imine oxidative coupling. Unique metal metal bonds are a consequence of the chelation.
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