Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 1, Pages 186-189Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja210365j
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- Stanford University
- Air Force Office of Scientific Research [FA9550-11-1-0293]
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The rearrangement of cis-stilbene oxide catalyzed by Al2O3 was studied in the presence of interfacial electric fields. Thin films of Al2O3 deposited on Si electrodes were used as the opposing walls of a reaction vessel. Application of a voltage across the electrodes engendered electrochemical double layer formation at the Al2O3-solution interface. The aldehyde to ketone product ratio of the rearrangement was increased by up to a factor of 63 as the magnitude of the double layer charge density was increased. The results support a field-dipole effect on the selectivity of the catalytic reaction.
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