4.8 Article

An Organometallic Sandwich Lanthanide Single-Ion Magnet with an Unusual Multiple Relaxation Mechanism

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 48, Pages 19286-19289

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja207891y

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Funding

  1. University of Ottawa
  2. NSERC
  3. CFI
  4. FFCR

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A dysprosium(III) sandwich complex, [Dy-III(COT '')(2)Li(THE)(DME)], was synthesized using 1,4-bis(trimethylsilyl)cyclooctatetraenyl dianion (COT ''). The complex behaves as a single-ion magnet and demonstrates unusual multiple relaxation modes. The observed relaxation pathways strongly depend on the applied static dc fields.

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