Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 2, Pages 916-919Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja211069f
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Funding
- JSPS
- MEXT (Japan)
- Grants-in-Aid for Scientific Research [22106519, 22750093, 21000006] Funding Source: KAKEN
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Catalytic asymmetric synthesis of axially chiral o-iodoacrylanilides and N-allyl-o-iodoanilides as useful chiral building blocks was achieved via chiral quaternary ammonium salt-catalyzed N-alkylations under phase-transfer conditions. The transition-state structure for the present reaction is discussed on the basis of the X-ray crystal structure of ammonium anilide.
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