Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 48, Pages 19350-19353Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2093579
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Funding
- ACS PRF [49817-ND1]
- NIH [GM095666, RR08389-01, RA13866-01]
- Sloan Foundation
- Beckman Foundation
- Research Corporation
- NSF [CHE-9208463, CHE-9629688]
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Ruthenium(II) polypyridyl complexes promote the efficient radical cation Diels-Alder cycloaddition of electron-rich dienophiles upon irradiation with visible light. These reactions enable facile [4 + 2] cycloadditions that would be electronically mismatched under thermal conditions. Key to the success of this methodology is the availability of ligand-modified ruthenium complexes that enable rational tuning of the electrochemical properties of the catalyst without significantly perturbing the overall photophysical properties of the system.
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