Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 6, Pages 1760-1762Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja108396k
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Funding
- NSF [CHE-0952753]
- NIH-NIGMS [GM088237]
- NSC of Taiwan [NSC-972917I564145]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0952753] Funding Source: National Science Foundation
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A chemo- and regioselective alpha-hydroxylation reaction of carbonyl compounds with molecular oxygen as oxidant is reported. The hydroxylation reaction is catalyzed by a dinuclear Pd(II) complex, which functions as an oxygen transfer catalyst, reminiscent of an oxygenase. The development of this oxidation reaction was inspired by discovery and mechanism evaluation of previously unknown Pd-(III)-Pd(III) complexes.
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