Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 30, Pages 11438-11441Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2037029
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Funding
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT) [2107, 21108011]
- global COE program (GCOE)
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [21108011] Funding Source: KAKEN
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A new M2L4 molecular capsule with an aromatic shell was prepared using two Pd(II) ions and four bisanthracene ligands. The self-assembled capsule possesses a cavity with a diameter of similar to 1 nm that can encapsulate medium-sized spherical and planar molecules as well as a very large molecule (C-60) in quantitative yields. The encapsulated guests are fully segregated and shielded from the external environment by the large anthracene panels.
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