4.8 Article

Lattice Distortion Oriented Angular Self-Assembly of Monolayer Titania Sheets

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 4, Pages 695-697

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja109314u

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Funding

  1. Australia Research Council
  2. Queensland Government
  3. International Fellowship
  4. Western Institute of Nanoelectronics (WIN)
  5. Center on Functional Engineered Nano Architectonics (FENA)
  6. University of California at Los Angeles
  7. University of Queensland

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Self-assembly of exfoliated monolayer titania sheets is investigated by detailed transmission electron microscopy and the force field calculations. It is demonstrated for the first time that slight but significant lattice distortions result in modified angular self-assembly of exfoliated monolayer Ti0.87O2 sheets. These findings significantly broaden current knowledge of the self-assembly of exfoliated nanoscale layered sheets, which may render the potential manipulation of self-assembly of nanosheets.

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