4.8 Article

Real-Time NMR Studies of Electrochemical Double-Layer Capacitors

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 48, Pages 19270-19273

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja2072115

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Funding

  1. Deutscher Akademischer Austauschdienst
  2. NYSERDA
  3. EU ERC
  4. US Department of Energy, Office of Basic Energy Sciences [DE-SC0001294]
  5. DOE Energy Frontier Research Center

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(11)B NMR spectroscopy has been used to investigate the sorption of BF(4)(-) anions on a highly porous, high surface area carbon, and different binding sites have been identified. By implementing in situ NMR approaches, the migration of ions between the electrodes of the supercapacitors and changes in the nature of ion binding to the surface have been observed in real time.

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