Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 24, Pages 9286-9289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2041942
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Funding
- Welch Foundation [E-1571]
- National Institute of General Medical Sciences [R01GM077635]
- A. P. Sloan Foundation
- Camille and Henry Dreyfus Foundation
- Norman Hackerman Advanced Research Program
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A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP2Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.
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