4.8 Article

Highly Efficient Catalytic Microengines: Template Electrosynthesis of Polyaniline/Platinum Microtubes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 31, Pages 11862-11864

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja203773g

Keywords

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Funding

  1. National Science Foundation [CBET 0853375]
  2. DOE BES [DE-SC0004937]
  3. Government of Catalonia
  4. U.S. Department of Energy (DOE) [DE-SC0004937] Funding Source: U.S. Department of Energy (DOE)
  5. Directorate For Engineering
  6. Div Of Chem, Bioeng, Env, & Transp Sys [0853375] Funding Source: National Science Foundation

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Highly efficient catalytic microtubular engines are synthesized rapidly and inexpensively using an electrochemical growth of bilayer polyaniline/platinum microtubes within the conically shaped pores of a polycarbonate template membrane. These mass-produced microtubular engines are only 8 mu m long, are self-propelled at an ultrafast speed (of over 350 body lengths s(-1)), and can operate in very low levels of the hydrogen peroxide fuel (down to 0.2%). The propulsion characteristics and optimization of these microtubular engines are described, along with their efficient operation in different biological environments which holds great promise for biomedical applications.

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