Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 17, Pages 6497-6500Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja110940c
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Funding
- Japan Society for the Promotion of Science (JSPS) [17390002]
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) [19790005]
- Grants-in-Aid for Scientific Research [17390002, 21390001, 19790005] Funding Source: KAKEN
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5- Fluoro-2-azaadamantane N-oxyl (5-FAZADO) realizes a simple, organocatalytic aerobic alcohol oxidation system that has a wide scope under mild conditions at ambient pressure and temperature and is weakly acidic and halogen- and transition-metal-free. The oxoammonium nitrate (5-F-AZADO(+)NO(3)(-)) works as a bifunctional catalyst of 5-F-AZADO and NO(x) that enables the catalytic aerobic oxidation of alcohols by itself (a metal-salt-free system).
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