Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 5, Pages 1232-1235Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1092216
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Funding
- MEXT, Japan [21245023, 22750083]
- Grants-in-Aid for Scientific Research [21245023, 22750083] Funding Source: KAKEN
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Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH2CH(CH(2)FG)- units.
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