4.8 Article

A Multifunctional Organic-Inorganic Hybrid Structure Based on MnIII-Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 1, Pages 87-90

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja209196t

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Funding

  1. NNSF of China [21073158]
  2. Zhejiang Provincial Natural Science Foundation of China [Z4100038]
  3. Fundamental Research Funds for the Central Universities [2010QNA3013]
  4. DOE [DE-FG02-08ER46491]

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A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn-III-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.

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