Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 19, Pages 7358-7360Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja202055v
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Funding
- Office of Science, Office of Basic Energy Sciences
- Division of Chemical Sciences, Geosciences, and Biosciences of the U.S. Department of Energy at LBNL [DE-AC02-05CH11231]
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Gold(I)-phosphine complexes are readily encapsulated by a tetrahedral supramolecular host (Ga4L6). We have investigated the catalytic activity of the resulting complexes for the intramolecular hydroalkoxylation of allenes. The catalytic activity of Me3PAuBr was increased 8-fold by encapsulation, as determined by initial rate kinetics, and we observed up to 67 catalytic turnovers by Me3PAu+ encapsulated in Ga4L6.
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