Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 14, Pages 5228-5231Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja200553m
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Funding
- Dow Chemical Company
- U.S. Department of Energy [DE-FG02-03ER15457]
- U.S. Department of Energy (DOE) [DE-FG02-03ER15457] Funding Source: U.S. Department of Energy (DOE)
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A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5-tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.
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