Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 4, Pages 774-776Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja110192b
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Funding
- NSF CRIF [CHE-0639094, CHE-0541745]
- California Institute of Technology
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An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.
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