4.8 Article

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 8, Pages 2386-2389

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja1108613

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Funding

  1. DFG, the International Research Training Group [IRTG 1038]
  2. Fonds der Chemischen Industrie
  3. Krupp Foundation
  4. Humboldt Foundation

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A new method for the preparation of a wide range of branched allylic esters from terminal alkynes that proceeds via a redox-neutral propargylic CH activation employing a rhodium(I)/DPEphos catalyst is reported.

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