Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 26, Pages 10074-10077Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja204344e
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Funding
- Alexander von Humboldt Foundation
- Australian Research Council [DP0665057]
- American Chemical Society
- U.S. Air Force Asian Office of Aerospace Research and Development
- Berlin Cluster of Excellence
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0844567] Funding Source: National Science Foundation
- Australian Research Council [DP0665057] Funding Source: Australian Research Council
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Stoichiometric reduction of the bulky beta-diketiminato germanium(II) chloride complex [((But)Nacnac)-GeCl] ((But)Nacnac = [{N(Dip)C(Bu-t)}(2)CH](-), Dip = C6H3Pr2i-2,6) with either sodium naphthalenide or the magnesium(I) dimer [{((Mes)Nacnac)Mg}(2)] ((Mes)Nacnac = [(MesNCMe)(2)CH](-), Mes = mesityl) afforded the radical complex [((But)Nacnac)Ge](.) in moderate yields. X-ray crystallographic, EPR/ENDOR spectroscopic, computational, and reactivity studies revealed this to be the first authenticated monomeric, neutral germanium(I) radical.
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