4.8 Article

Chiral Transformation: From Single Nanowire to Double Helix

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 50, Pages 20060-20063

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja208121c

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Funding

  1. MOE [ARC 13/09]
  2. A*Star of Singapore [102-152-0018]

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We report a new type of water-soluble ultrathin Au-Ag alloy nanowire (NW), which exhibits unprecedented behavior in a colloidal solution. Upon growth of a thin metal (Pd, Pt, or Au) layer, the NW winds around itself to give a metallic double helix. We propose that the winding originates from the chirality within the as-synthesized Au-Ag NWs, which were induced to untwist upon metal deposition.

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