Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 38, Pages 14848-14851Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2032822
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
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A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI2 exhibits a 3D lattice fence topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hinged structure model presented here can also be applied to other lattice fence topologies with little or no modification, depending on the symmetry of the molecular building blocks.
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