4.8 Article

Iodinated Aluminum(III) Corroles with Long-Lived Triplet Excited States

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 33, Pages 12899-12901

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja202692b

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Funding

  1. U.S.-Israel Binational Science Foundation (BSF)

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The first reported iodination of a corrole leads to selective functionalization of the four C-H bonds on one pole of the macrocycle. An aluminum(III) complex of the tetraiodinated corrole, which exhibits red fluorescence, possesses a long-lived triplet excited state.

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