4.8 Article

An Unusual Hydrogen Migration/C-H Activation Reaction with Group 3 Metals

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 133, Issue 13, Pages 4680-4683

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja110505r

Keywords

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Funding

  1. UCLA
  2. Sloan Foundation
  3. NSF [CHE-0847735]
  4. ARO-DURIP
  5. ONR-DURIP
  6. DOE [DE-PS36-08GO98004P]
  7. Direct For Mathematical & Physical Scien [0847735] Funding Source: National Science Foundation
  8. Division Of Chemistry [0847735] Funding Source: National Science Foundation

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A novel hydrogen migration from the phenyl ring to the pyridine ring of an yttrium pyridyl complex supported by a 1,1'-ferrocene diamide ligand is reported. Density functional theory calculations were instrumental in probing the mechanism for this transformation.

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